Have you ever tried defrosting your windows, and it just doesn't work with the heat. So you try cold air, and that doesnt work, so then you put the heat and defroster on with the air conditioner, and magically, it defrosts! Well, it just so happens that the conditioned air helps defrost the windows, so now car companies decided to turn on the AC automatically for you when you put the defrost on so you don't have to. So don't worry, you don't have anything wrong with your car!